You could use a '69 or '70.The threads are different :1/4" x20 UNC bolts to hold the rocker covers;you'd need 4 new bolts.1/4" UNF nuts on the intake flanges.Otherwise they're the same.
If you use an earlier head ('63-'67),you still have 1/4" x 26 tpi threads.Valve sizes are smaller before mid-'67,but there's enough metal to cut the seats to the larger size (if it hasn't been done already).Some like the small-valve heads better.I like the idea of a smaller exhaust valve.
Valve springs are different on the earlier heads,but you just need to use the right lower spring collars with the right springs.
If you use an earlier head,it would be a good idea to change the intake flanges for the later ones with shouldered bolts and rubber washers.
Most heads had a manufacture date cast in an oval between the intake valves. "66" would mean a '67 model. They stopped doing that ;some later heads have the oval mark with no numbers.They still have a casting number,like "E 3663" to identify them.
'71- early '72 heads might not seal so well around the rocker box,even if you remove the roll-pins.I'm not sure if there's enough metal to suit the earlier rocker box.Late '72-'74 9-bolt heads would have the same problem (if it is a problem),but they also use different exhaust pipes (push-in,instead of spigot mounted),and they have a different intake flange arrangement.You could fit exhaust spigots,but the intake flanges would be obviously later than '68.