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I've done quite a bit of wetsanding and aluminum polishing in my day. I highly recommend not putting any kind of clearcoat or powdercoat over the aluminum. Aluminum oxidation is nothing close to as bad as iron oxidation. As stated before, aluminum just turns kind of chalky but that is over many years and if not taken care of, could pit from salt as well. A big problem with putting a clearcoat over aluminum is it usually will pit/peel. Look at some aluminum rims on some of the cars here in WI, most of them look like ***** due to the clearcoat peeling, which can be started from just a knick. The clearcoat on the valvecovers of my Thrux aren't really peeling but looks like it might start soon right around where the gasket is, I'm assuming that is due to the heat. Keep the aluminum bare, polish it with Mothers metal polish everyonce in awhile to brighten it up, that is all you have to do!
What are you making now by the way? If you wanted the aluminum to exactly match the look of the stock engine covers, headlight brackets, etc... then you'd have to create some minor scratches in the aluminum (using a more coarse sandpaper such as 800 or something) to give it the "brushed" look and then clear coat it.
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