Kurt,
Head to your local library or find their website. Then do a search for anything related to Triumphs or Brit bikes. This is what I did when I got my first Triumph. My local library is part of an association of many libraries and they were able to borrow a good book from a library downstate. I had it for 2 weeks and devoured the contents, which established a good baseline of knowledge. I think that would be a good way to start. The book is the Illustrated Triumph Buyer's Guide by Roy Bacon.
Check out the technical section of this forum because there are a number of write-ups that will impart further knowledge. Plus many of the members here have a lot of knowledge so when you get your bike, they can help you with issues you cannot resolve or understand without some help.
Here is a link to a site with many parts and service manuals.
http://classicbike.biz/Triumph/Triumph.htm
Nothing like exploded assembly dwgs to give you a clear picture on a particular assembly or system. Will probably answer a lot of your questions as they arise.
Hope this helps.
Rob